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Registry Hub
Peer-Reviewed Evidence
HomeDrug RegistryCompareCHLORZOXAZONE vs ACULAR PRESERVATIVE FREE
Comparative Pharmacology

CHLORZOXAZONE vs ACULAR PRESERVATIVE FREE Comparison

Head-to-head clinical analysis & difference comparison: details on mechanism of action, dosing, half-life, interactions, and maternal-fetal safety.

Clinical EssentialsPharmacokineticsSpecial PopulationsSafety & MonitoringPregnancy & LactationClinical Insights
Differential Analysis

CHLORZOXAZONE vs ACULAR PRESERVATIVE FREE

Clinician-reviewed, head-to-head comparison of mechanism, dosing, pharmacokinetics, and safety profiles.

View CHLORZOXAZONE Monograph View ACULAR PRESERVATIVE FREE Monograph
CHLORZOXAZONE
Skeletal Muscle Relaxant
Category C
ACULAR PRESERVATIVE FREE
NSAID Ophthalmic
Category C
TL;DR — Key Differences
  • Drug class: CHLORZOXAZONE is a Skeletal Muscle Relaxant; ACULAR PRESERVATIVE FREE is a NSAID Ophthalmic.
  • Half-life: CHLORZOXAZONE has a half-life of Terminal elimination half-life approximately 1–2 hours; clinically relevant for muscle relaxant effect duration.; ACULAR PRESERVATIVE FREE has Terminal elimination half-life is approximately 5-6 hours in adults, but can be prolonged in elderly patients (up to 8-9 hours) and in patients with renal impairment (up to 13-19 hours)..
  • No direct drug-drug interaction has been documented between CHLORZOXAZONE and ACULAR PRESERVATIVE FREE.
  • Pregnancy: CHLORZOXAZONE is rated Category C; ACULAR PRESERVATIVE FREE is rated Category C.

Last clinically reviewed: July 2026 · OpiCalc Medical Review Team

Clinical Essentials

CHLORZOXAZONE
ACULAR PRESERVATIVE FREE
Mechanism of Action
CHLORZOXAZONE

Chlorzoxazone acts centrally on the spinal cord and subcortical areas of the brain to inhibit multisynaptic reflex arcs involved in producing and maintaining muscle spasm. It may also have some sedative effects.

ACULAR PRESERVATIVE FREE

Ketorolac tromethamine is a nonsteroidal anti-inflammatory drug (NSAID) that inhibits cyclooxygenase (COX-1 and COX-2) enzymes, thereby reducing prostaglandin synthesis. It produces anti-inflammatory and analgesic effects.

Indications
CHLORZOXAZONE

Adjunct for relief of acute painful musculoskeletal conditions associated with muscle spasm

ACULAR PRESERVATIVE FREE

FDA-approved: Treatment of ocular inflammation and pain following cataract surgery and corneal refractive surgery.,Off-label: Relief of seasonal allergic conjunctivitis symptoms, management of cystoid macular edema, and treatment of postoperative inflammation in other ocular procedures.

Standard Dosing
CHLORZOXAZONE

250-500 mg orally 3-4 times daily, maximum 750 mg 4 times daily.

ACULAR PRESERVATIVE FREE

1 drop into affected eye(s) four times daily (every 6 hours). Instill into conjunctival sac. Shake well before use.

Direct Interaction
CHLORZOXAZONE
No Direct Interaction
ACULAR PRESERVATIVE FREE
No Direct Interaction

Pharmacokinetics

CHLORZOXAZONE
ACULAR PRESERVATIVE FREE
Half-Life
CHLORZOXAZONE

Terminal elimination half-life approximately 1–2 hours; clinically relevant for muscle relaxant effect duration.

ACULAR PRESERVATIVE FREE

Terminal elimination half-life is approximately 5-6 hours in adults, but can be prolonged in elderly patients (up to 8-9 hours) and in patients with renal impairment (up to 13-19 hours).

Metabolism
CHLORZOXAZONE

Hepatic, primarily via CYP2E1, also CYP1A2 and CYP3A4

ACULAR PRESERVATIVE FREE

Ketorolac undergoes hepatic metabolism via hydroxylation and conjugation (glucuronidation) to inactive metabolites. It is primarily metabolized by CYP2D6 and CYP3A4 isoenzymes, with renal excretion of metabolites and unchanged drug.

Excretion
CHLORZOXAZONE

Primarily hepatic metabolism followed by renal excretion of metabolites; <1% excreted unchanged in urine; minor biliary/fecal elimination.

ACULAR PRESERVATIVE FREE

Primarily renal excretion of metabolites and unchanged drug; approximately 80% of a dose is excreted in urine as ketorolac and its hydroxy metabolites, with about 6% excreted in feces.

Protein Binding
CHLORZOXAZONE

Approximately 90–95% bound, primarily to albumin.

ACULAR PRESERVATIVE FREE

99% bound to plasma proteins, primarily albumin.

VD (L/kg)
CHLORZOXAZONE

0.46–0.64 L/kg; indicates distribution into total body water.

ACULAR PRESERVATIVE FREE

0.15-0.25 L/kg after oral administration; for ophthalmic use, systemic absorption is minimal, so Vd is not clinically meaningful.

Bioavailability
CHLORZOXAZONE

Oral: nearly complete; rapidly absorbed with extensive first-pass metabolism; systemic bioavailability approximately 30–50% due to first-pass effect.

ACULAR PRESERVATIVE FREE

Ophthalmic administration: Systemic bioavailability is approximately 0.5-1% after ocular instillation due to low corneal penetration and rapid clearance; oral bioavailability is 100%.

Special Populations

CHLORZOXAZONE
ACULAR PRESERVATIVE FREE
Renal Adjustments
CHLORZOXAZONE

No specific guidelines; use with caution in severe renal impairment (GFR <30 m L/min) due to potential accumulation of active metabolite.

ACULAR PRESERVATIVE FREE

No dosage adjustment required for renal impairment. Drug is minimally absorbed systemically.

Hepatic Adjustments
CHLORZOXAZONE

Contraindicated in hepatic impairment; avoid use in Child-Pugh class B or C due to risk of hepatotoxicity.

ACULAR PRESERVATIVE FREE

No dosage adjustment required for hepatic impairment. Drug is minimally absorbed systemically.

Pediatric Dosing
CHLORZOXAZONE

Not established; safety and efficacy not studied in pediatric patients.

ACULAR PRESERVATIVE FREE

Children ≥3 years: 1 drop into affected eye(s) four times daily. Safety and efficacy in children <3 years not established.

Geriatric Dosing
CHLORZOXAZONE

Initiate at lower end of dosing range (250 mg 3-4 times daily); monitor for CNS effects (dizziness, drowsiness) and liver function.

ACULAR PRESERVATIVE FREE

No specific dosage adjustment required. Use same dose as adults; monitor for tolerability.

Safety & Monitoring

CHLORZOXAZONE
ACULAR PRESERVATIVE FREE
Black Box Warnings
CHLORZOXAZONE
FDA Black Box Warning

None

ACULAR PRESERVATIVE FREE
FDA Black Box Warning

NSAIDs may increase the risk of serious cardiovascular events (e.g., myocardial infarction, stroke) and gastrointestinal events (e.g., bleeding, ulceration, perforation). However, due to low systemic absorption with ophthalmic use, this boxed warning is less clinically relevant but still applies.

Warnings/Precautions
CHLORZOXAZONE

May cause drowsiness, dizziness, or impaired coordination. Caution in patients with hepatic impairment. Discontinue if hypersensitivity reactions occur. Avoid concurrent use with alcohol or other CNS depressants.

ACULAR PRESERVATIVE FREE

Use with caution in patients with compromised ocular surface, history of herpes simplex keratitis, bleeding tendencies, or those on anticoagulants. Prolonged use may delay wound healing. Monitor for signs of corneal epithelial breakdown or infection.

Contraindications
CHLORZOXAZONE

Hypersensitivity to chlorzoxazone or any component of the formulation; impaired hepatic function

ACULAR PRESERVATIVE FREE

Hypersensitivity to ketorolac or any component of the formulation; patients with active ocular infection or advanced dry eye; history of asthma, urticaria, or allergic-type reactions to aspirin or other NSAIDs.

Adverse Reactions
CHLORZOXAZONE
Data Pending
ACULAR PRESERVATIVE FREE
Data Pending
Food Interactions
CHLORZOXAZONE

No significant food interactions. Take with or without food. Grapefruit juice may increase drug levels; avoid large quantities.

ACULAR PRESERVATIVE FREE

No known food interactions. No dietary restrictions required.

Pregnancy & Lactation

CHLORZOXAZONE
ACULAR PRESERVATIVE FREE
Teratogenic Risk
CHLORZOXAZONE

Teratogenic risk in humans is not well-studied. No major teratogenic effects have been reported in animal studies. However, as with all medications, use during pregnancy only if clearly needed and after weighing risks vs. benefits. Avoid during first trimester unless necessary.

ACULAR PRESERVATIVE FREE

FDA Pregnancy Category C. No adequate studies in pregnant women. In animal studies, ketorolac tromethamine (active ingredient) was not teratogenic in rats or rabbits at doses up to 1.5-3 times the human exposure. However, because NSAIDs can cause premature closure of the ductus arteriosus and oligohydramnios in the third trimester, use is contraindicated after 30 weeks gestation. In first and second trimesters, use only if potential benefit justifies potential fetal risk.

Lactation Summary
CHLORZOXAZONE

Not recommended during breastfeeding due to potential for sedation in the infant. No M/P ratio data available.

ACULAR PRESERVATIVE FREE

Ketorolac is excreted in human milk following oral administration. After a single intramuscular dose of 10 mg, the milk-to-plasma (M/P) ratio was 0.037. Low levels are expected in breastmilk; however, due to potential adverse effects of NSAIDs on neonates, caution is advised. Use is generally avoided in nursing mothers, especially with premature infants or those with thrombocytopenia or renal impairment.

Pregnancy Dosing
CHLORZOXAZONE

No dosage adjustment specific to pregnancy is required based on pharmacokinetic data; however, clinical response should be monitored.

ACULAR PRESERVATIVE FREE

No specific pharmacokinetic studies in pregnancy. Dosing should be at the lowest effective dose for the shortest duration. Avoid use after 30 weeks gestation. No adjustment for first or second trimester unless renal function changes.

Maternal Safety Status
CHLORZOXAZONE
Category C
ACULAR PRESERVATIVE FREE
Category C

Clinical Insights

CHLORZOXAZONE
ACULAR PRESERVATIVE FREE
Clinical Pearls
CHLORZOXAZONE

Chlorzoxazone is a centrally acting muscle relaxant used for acute musculoskeletal pain. Onset of action is within 1 hour; peak effect at 1-2 hours. Monitor for hepatotoxicity, especially with prolonged use or high doses. Can cause drowsiness and impair motor skills; avoid concurrent use with alcohol or other CNS depressants. Tablets may be crushed for patients with swallowing difficulties.

ACULAR PRESERVATIVE FREE

ACULAR (ketorolac tromethamine ophthalmic solution) is an NSAID for ocular use. Preservative-free formulation is indicated for single-use to avoid corneal toxicity. Apply with caution in patients with bleeding disorders or those on anticoagulants due to risk of ocular bleeding. Prolonged use may delay corneal healing. Monitor for signs of keratitis or conjunctival hyperemia.

Patient Counseling
CHLORZOXAZONE

Take exactly as prescribed; do not increase dose or frequency.,May cause drowsiness or dizziness; avoid driving or operating machinery until you know how it affects you.,Avoid alcohol and other CNS depressants while taking this medication.,Report signs of liver problems: dark urine, yellowing of eyes/skin, persistent nausea, abdominal pain.,Do not suddenly stop taking if used long-term; taper under medical supervision to avoid withdrawal.

ACULAR PRESERVATIVE FREE

Use exactly as prescribed; do not touch the dropper tip to any surface to avoid contamination.,Each single-use vial is for one dose only; discard after use to prevent infection.,Remove contact lenses before instillation and wait 10 minutes before reinserting.,Do not drive or operate machinery if vision is blurry after application.,Report eye pain, increased redness, or vision changes to your doctor immediately.

Safety Verification

Known Interactions

CHLORZOXAZONE Risks3
Lumacaftor + Chlorzoxazone
moderate

"Lumacaftor is a strong inducer of cytochrome P450 (CYP) 3A4 and other drug-metabolizing enzymes, including CYP2E1. Chlorzoxazone is primarily metabolized by CYP2E1 to its inactive metabolite. Concomitant use increases CYP2E1 activity, leading to accelerated chlorzoxazone clearance and reduced systemic exposure, potentially diminishing its therapeutic effect as a muscle relaxant."

Chlorzoxazone + Diltiazem
moderate

"Chlorzoxazone, a centrally acting muscle relaxant, inhibits the metabolism of diltiazem, a calcium channel blocker, via competitive inhibition of CYP3A4. This leads to increased plasma concentrations of diltiazem, potentially causing enhanced negative chronotropic and vasodilatory effects, resulting in bradycardia, hypotension, or atrioventricular block. Patients may experience dizziness, syncope, or exacerbate heart failure symptoms."

Butalbital + Chlorzoxazone
moderate

"Butalbital, a barbiturate, induces hepatic cytochrome P450 enzymes (particularly CYP2E1), accelerating the metabolism of chlorzoxazone, a centrally acting muscle relaxant primarily metabolized by CYP2E1. This results in reduced plasma concentrations of chlorzoxazone, leading to diminished therapeutic efficacy and potential loss of symptom control. Clinically, patients may experience inadequate muscle relaxation, requiring dose adjustments or alternative therapy."

ACULAR PRESERVATIVE FREE Risks

No interactions on record

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Clinical Q&A

Frequently Asked Questions

Common clinical questions about CHLORZOXAZONE vs ACULAR PRESERVATIVE FREE, answered by our medical review team.

1. What is the main difference between CHLORZOXAZONE and ACULAR PRESERVATIVE FREE?

CHLORZOXAZONE is a Skeletal Muscle Relaxant that works by Chlorzoxazone acts centrally on the spinal cord and subcortical areas of the brain to inhibit multisynaptic reflex arcs involved in producing and maintaining muscle spasm. It may also have some sedative effects.. ACULAR PRESERVATIVE FREE is a NSAID Ophthalmic that works by Ketorolac tromethamine is a nonsteroidal anti-inflammatory drug (NSAID) that inhibits cyclooxygenase (COX-1 and COX-2) enzymes, thereby reducing prostaglandin synthesis. It produces anti-inflammatory and analgesic effects.. They differ in pharmacokinetic profiles, FDA-approved indications, and side effect profiles.

2. Which is stronger: CHLORZOXAZONE or ACULAR PRESERVATIVE FREE?

Potency comparisons between CHLORZOXAZONE and ACULAR PRESERVATIVE FREE depend on the specific clinical indication. These are agents from distinct pharmacological classes and are not directly interchangeable by dose. A physician or clinical pharmacist should guide any therapeutic switching decisions.

3. What is the standard dosing for CHLORZOXAZONE vs ACULAR PRESERVATIVE FREE?

The standard adult dose of CHLORZOXAZONE is: 250-500 mg orally 3-4 times daily, maximum 750 mg 4 times daily.. The standard adult dose of ACULAR PRESERVATIVE FREE is: 1 drop into affected eye(s) four times daily (every 6 hours). Instill into conjunctival sac. Shake well before use.. Dosing should always be individualized based on indication, renal and hepatic function, age, and other patient factors.

4. Can you take CHLORZOXAZONE and ACULAR PRESERVATIVE FREE together?

No direct drug-drug interaction has been formally documented between CHLORZOXAZONE and ACULAR PRESERVATIVE FREE in current clinical databases. However, individual patient risk factors including other medications, organ function, and comorbidities should always be evaluated by a qualified healthcare provider.

5. Are CHLORZOXAZONE and ACULAR PRESERVATIVE FREE safe during pregnancy?

The maternal-fetal safety profiles differ. CHLORZOXAZONE is classified as Category C. Teratogenic risk in humans is not well-studied. No major teratogenic effects have been reported in animal studies. However, as with all medications, use during pregnancy only if cl. ACULAR PRESERVATIVE FREE is classified as Category C. FDA Pregnancy Category C. No adequate studies in pregnant women. In animal studies, ketorolac tromethamine (active ingredient) was not teratogenic in rats or rabbits at doses up to. Always consult a maternal-fetal medicine specialist before taking either drug during pregnancy or lactation.