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Chelating Agent/Prescription

DEPEN

DEPEN

Clinical safety rating

caution

Comprehensive clinical and safety monograph for DEPEN (DEPEN).


Mechanism of Action

Penicillamine is a chelating agent that forms soluble complexes with heavy metals (e.g., copper, mercury, lead) and promotes their renal excretion. In rheumatoid arthritis, it reduces rheumatoid factor and immune complexes, and inhibits collagen cross-linking.

What the body does with it

MetabolismPenicillamine is metabolized via oxidation to disulfides. It is primarily excreted in urine as unchanged drug and metabolites.
ExcretionRenal: 50% as unchanged drug; biliary/fecal: minor, <5%.
Half-life1.5-4 hours; prolonged to 6-12 hours in renal impairment; clinical context: dosing interval adjustments needed in CKD.
Protein binding80%; primarily to albumin.
Volume of Distribution0.1-0.4 L/kg; indicates limited extravascular distribution, mainly confined to plasma and interstitial fluid.
BioavailabilityOral: 40-70% (variable due to food and formulation).
Onset of ActionOral: 1-2 hours for chelation effect in Wilson disease; IV: immediate for heavy metal chelation.
Duration of Action4-6 hours for chelation effect; may persist up to 12 hours in renal impairment.
Molecular Weight135.23

Classification & Brands

Dosing & administration

250 mg orally 4 times daily, target dose 1000-1500 mg/day in divided doses.

Dosage formTABLET
Renal impairmentGFR 30-59 mL/min: 250 mg every 8-12 hours; GFR 15-29 mL/min: 250 mg every 12-24 hours; GFR <15 mL/min: 250 mg every 24 hours or avoid use.
Liver impairmentNo adjustment recommended for mild to moderate impairment (Child-Pugh A or B); avoid use in severe impairment (Child-Pugh C) due to increased risk of hepatotoxicity.
Pediatric useChildren >1 year: 10-15 mg/kg/day divided every 6-8 hours, maximum 500 mg/day.
Geriatric useStart at lower end of dosing range (250 mg twice daily) due to age-related renal function decline; monitor renal function and adjust based on creatinine clearance.

Use during pregnancy

1st trimesterRisk of congenital anomalies, especially orofacial clefts and neural tube defects.
2nd trimesterRisk of fetal hepatotoxicity and intrauterine growth restriction.
3rd trimesterRisk of neonatal hepatotoxicity and coagulopathy.

Clinical note

Comprehensive clinical and safety monograph for DEPEN (DEPEN).

Placental transferCrosses placenta; fetal concentrations can reach maternal levels after multiple doses.
BreastfeedingNot recommended due to excretion into breast milk and risk of neonatal hepatotoxicity.
Lactation RatingL5
Teratogenic RiskPenicillamine (Depen) is associated with severe fetal malformations including cutis laxa and skeletal abnormalities when used during pregnancy. First trimester exposure carries highest risk; use is contraindicated unless necessary for maternal conditions like Wilson's disease or cystinuria. Second and third trimester use may cause fetal connective tissue disorders.
Fetal MonitoringMonitor maternal renal function, CBC, and urinalysis monthly. Fetal ultrasound for skeletal anomalies. In Wilson's disease, monitor serum copper levels and neurological status.
Fertility EffectsNo significant adverse effects on fertility reported in humans. Animal studies suggest no impairment.

Warnings & precautions

■ FDA Black Box Warning

None.

Side Effect Profile

Serious Effects

Absolute Contraindications

Hypersensitivity to penicillamineHistory of penicillamine-induced aplastic anemia or agranulocytosisPregnancy (relative contraindication, but may be used for Wilson disease with caution)

Clinical Precautions

PrecautionsBone marrow suppression (leukopenia, thrombocytopenia, aplastic anemia), Proteinuria and nephrotic syndrome, Autoimmune reactions (lupus-like syndrome, myasthenia gravis), Hepatotoxicity, Severe skin reactions (e.g., pemphigus, Stevens-Johnson syndrome), Monitor renal function, blood counts, and urinalysis regularly
Food/DietaryAvoid foods high in copper (e.g., liver, shellfish, nuts, chocolate, mushrooms) during treatment for Wilson disease. For cystinuria, maintain high fluid intake (at least 3-4 liters/day) and reduce sodium and animal protein to decrease cystine excretion. Vitamin B6 supplementation may be needed as DEPEN can increase pyridoxine requirements.

Clinical Tips & Counseling

Clinical PearlsDEPEN (penicillamine) is a chelating agent used for Wilson disease, cystinuria, and rheumatoid arthritis. Monitor for proteinuria and hematuria due to immune complex nephropathy. Cross-sensitivity with penicillin possible. Administer on empty stomach for Wilson disease; with meals for cystinuria to reduce GI upset. Avoid concomitant use with other nephrotoxic drugs.
Patient AdviceTake DEPEN on an empty stomach at least 1 hour before or 2 hours after meals, unless otherwise directed for cystinuria. · Do not skip doses; consistent intake is critical for Wilson disease to prevent copper accumulation. · Report any signs of infection, unusual bleeding, skin rash, or changes in urine color or output immediately. · Avoid alcohol completely as it may increase risk of liver toxicity. · Use effective contraception during therapy as DEPEN can cause fetal harm. · Have regular blood and urine tests as ordered to monitor for side effects.

DEPEN Interactions

Loading safety data…

This overview is compiled from peer-reviewed clinical sources and FDA labeling. It's here to support — not replace — clinical judgment. Always verify dosing against your institution's current protocols before prescribing.

On this page

Mechanism of ActionDosing & administrationUse during pregnancyWarnings & precautionsDrug interactions

Compare with

BAFIERTAMBALCALCIUM DISODIUM VERSENATECHEMETCUPRIMINE

External sources

DailyMed (NIH) PubMed OpenFDA